Blair, determined to have her Queen status at college, starts her first day at NYU along with Dan and Vanessa. However, Georgina, who was assigned as Blair's roommate, sets out to ensure that she does not retain her title. Serena gets ready to move into her dorm at Brown, but has a fight with Chuck before hand. This leads her to search out Chuck's enemy, Carter, to help her get even with him. Meanwhile, Nate and Bree's relationship continues to grow despite the tension their relationship could cause between their families.
Elenco: Blake Lively , Leighton Meester , Penn Badgley , Chace Crawford , Ed Westwick , Kelly Rutherford , Matthew Settle , Kaylee DeFer , Jessica Szohr , Kaylee De Fer , Kelly Rutherford , Kristen Bell , Matthew Settle , Michelle Trachtenberg , Taylor Momsen .